Synthesis and Characterization of Two Isostructural Lanthanide-Containing Metal-Organic Frameworks Constructed from an Unprecedented [Ln7(μ3-OH)8]13+ Cluster
Lianchao Liu
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
Search for more papers by this authorCorresponding Author
Chaojun Shen
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Chaojun Shen, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
Daqiang Yuan, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorFangfang Dong
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
Search for more papers by this authorWenjing Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorCorresponding Author
Daqiang Yuan
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Chaojun Shen, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
Daqiang Yuan, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorLianchao Liu
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
Search for more papers by this authorCorresponding Author
Chaojun Shen
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Chaojun Shen, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
Daqiang Yuan, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorFangfang Dong
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
Search for more papers by this authorWenjing Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorCorresponding Author
Daqiang Yuan
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Chaojun Shen, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
Daqiang Yuan, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorAbstract
Two isostructural metal-organic frameworks formulated as [Gd7(L)4(μ3-OH)8(HCOO)(DMF)6(H2O)]·DMF·H2O (1) and [Tb7(L)4(μ3-OH)8(HCOO)(DMF)5(H2O)]·DMF·H2O (2) (H3L=3,5-di(4′-carboxylphenyl)benzoic acid) have been synthesized and structurally characterized. The building blocks of the structures are the heptanuclear lanthanide clusters of the dicubane-like type [Ln7(μ3-OH)8]13+ (Ln=Gd, Tb) which are formally assembled into porous three-dimensional networks through the linkage of L. Variable temperature magnetic studies down to 2 K reveal antiferromagnetic interactions in complex 1. Furthermore, the fluorescence property of 2 was also studied.
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