Transfer Hydrogenation of Ethyl Levulinate to γ-Valerolactone Catalyzed by Iron Complexes
Nan Dai
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Search for more papers by this authorRui Shang
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Search for more papers by this authorMingchen Fu
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Search for more papers by this authorCorresponding Author
Yao Fu
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China, Tel.: 0086-0551-63607476; Fax: 0086-0551-63606689Search for more papers by this authorNan Dai
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Search for more papers by this authorRui Shang
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Search for more papers by this authorMingchen Fu
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Search for more papers by this authorCorresponding Author
Yao Fu
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China, Tel.: 0086-0551-63607476; Fax: 0086-0551-63606689Search for more papers by this authorAbstract
Conversion of biomass-derived ethyl levulinate to γ-valerolactone is realized by using homogeneous iron-catalyzed transfer hydrogenation (CTH). By utilizing Casey's catalyst and cheap isopropanol as hydrogen source, γ-valerolactone can be generated in 95% yield. Addition of catalytic amount of base is important to achieve good yield.
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