Study of Linear and Nonlinear Optical Properties of Four Derivatives of Substituted Aryl Hydrazones of 1,8-Naphthalimide
Peiyang Gu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorXufeng Xu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorFeng Zhou
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorTingting Zhao
Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore
Search for more papers by this authorGaojie Ye
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorGaoyan Liu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorQinghua Xu
Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore
Search for more papers by this authorJianfeng Ge
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorCorresponding Author
Qingfeng Xu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China, Tel.: 0086-0512-65880367Search for more papers by this authorCorresponding Author
Jianmei Lu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China, Tel.: 0086-0512-65880367Search for more papers by this authorPeiyang Gu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorXufeng Xu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorFeng Zhou
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorTingting Zhao
Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore
Search for more papers by this authorGaojie Ye
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorGaoyan Liu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorQinghua Xu
Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore
Search for more papers by this authorJianfeng Ge
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Search for more papers by this authorCorresponding Author
Qingfeng Xu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China, Tel.: 0086-0512-65880367Search for more papers by this authorCorresponding Author
Jianmei Lu
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
Department of Polymer Science, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China, Tel.: 0086-0512-65880367Search for more papers by this authorAbstract
Four 1,8-naphthalimide hydrazone molecules with different electron-donating groups have been applied in the study of linear and nonlinear optical (NLO) properties. These compounds showed strong green emission in solution. Their NLO properties such as two-photon absorption (TPA) behavior with femtosecond laser pulses ca. 800 nm and excited-state absorption (ESA) behavior with nanosecond laser pulses at 532 nm were investigated. Compound 4 presented the largest two-photon cross section (550 GM) among them due to two factors: the conjugated length of compound 4 is the longest and the electron-donating ability of compound 4 is the strongest. Different from TPA behavior, compound 2 showed the best nonlinear absorption properties at 532 nm and its nonlinear absorption coefficient and third-order nonlinear optical susceptibilities χ(3) were up to 1.41×10−10 MKS and 4.65×10−12 esu, respectively. Through the modification of the structure, the nonlinear optical properties of these compounds at different wavelengths (532 and 800 nm) were well tuned. The great broad-band nonlinear optical properties indicate hydrazones are good candidates for organic nonlinear optical absorption materials.
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