The supermolecular based on sodium molybdate(VI) and sulfate, dibenzo-18-crown-6 was synthesized in acetonitrile and characterized by elemental analysis, IR, ¹H NMR, single crystal X-ray diffraction, indicating that it contains [S₂Mo₁₈O₆₂]⁴⁺ and [Na(DB18C6)(H₂O)]⁺, where each sodium ion is deviated from the plane defined by the oxygen atoms in the corresponding crown ether. The compound crystallizes in the monoclinic space group C2/c with a=3.29332(10) nm, b=1.90917(6) nm, c=2.63132(7) nm, β=121.6630(10)°, V=14081.8(7) nm³, Z=8, T=293(2) K, and R₁ (wR₂)=0.0177 (0.1525). The compound exhibits a novel organic-inorganic structure, in which the crown ether-sodium complexes are coordinated to the terminal oxygen atoms of Mo₁₈O₅₄ and the oxygen atoms of water molecule.

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Volume30, Issue3

March, 2012

Pages 512-516

A Supermolecule Assembled by Sodium Cation, Crown Ether and α-Dawson Heteropolyanion

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A Supermolecule Assembled by Sodium Cation, Crown Ether and α-Dawson Heteropolyanion

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