Excess molar volumes V_m^Eand kinematic viscosities ν have been measured as a function of composition for binary mixtures of propylene glycol monomethyl ether (1-methoxy-2-propanol), MeOCH₂CH(OH)Me, propylene glycol monoethyl ether (1-ethoxy-2-propanol), EtOCH₂CH(OH)Me, propylene glycol monopropyl ether (1-propoxy-2-propanol), PrOCH₂CH(OH)Me, propylene glycol monobutyl ether (1-butoxy-2-propanol), BuOCH₂CH(OH)Me, and propylene glycol tert-butyl ether (1-tert-butoxy-2-propanol), t-BuOCH₂CH(OH)Me with 1-butanol, and 2-butanol, at 298.15 K and atmospheric pressure. The excess molar volumes are negative across the entire range ofcomposition for all the systems with 1-butanol, and positive for the systems 2-butanol+1-methoxy-2-propanol, and +1-propoxy-2-propanol, negative for the systems 2-butanol+1-butoxy-2-propanol, and change sign for the systems 2-butanol+1-ethoxy-2-propanol, and +1-tert-butoxy-2-propanol. From the experimental data, the deviation in dynamic viscosity η from Δx_iη_i has been calculated. Both excess molar volumes and viscosity deviations have been correlated using a Redlich-Kister type polynomial equation by the method of least-squares for the estimation of the binary coefficients and the standard errors.

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Volume25, Issue12

December, 2007

Pages 1781-1789

Excess Molar Volumes and Viscosities for Binary Mixtures of 1-Alkoxypropan-2-ols with 1-Butanol, and 2-Butanol at 298.15 K and Atmospheric Pressure

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Excess Molar Volumes and Viscosities for Binary Mixtures of 1-Alkoxypropan-2-ols with 1-Butanol, and 2-Butanol at 298.15 K and Atmospheric Pressure

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