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Environmentally Benign Oxidation of Some Organic Sulfides with 34% Hydrogen Peroxide Catalyzed by Simple Heteropolyoxometalates
Reza Tayebee, Mohammad Hassan Alizadeh,
Mohammad Hassan Alizadeh
Department of Chemistry, Ferdowsi University, Mashhad, 91779, Iran
Search for more papers by this authorReza Tayebee, Mohammad Hassan Alizadeh,
Mohammad Hassan Alizadeh
Department of Chemistry, Ferdowsi University, Mashhad, 91779, Iran
Search for more papers by this authorAbstract
An environmentally benign oxygenation protocol was developed for selective oxidation of some types of aromatic and aliphatic sulfides in good to excellent yields utilizing 34% hydrogen peroxide catalyzed by simple heteropolyoxometalates in normal drinking water at room temperature. The catalysts could be recovered and reused for at least seven reaction cycles under the described reaction conditions without considerable loss of reactivity. This procedure introduced a new insight into the use of simple heteropolyanions as recoverable catalysts for the oxidation of organic sulfides by an environmentally acceptable protocol.
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