Direct Synthesis, Crystal Structure and Thermal Kinetics of Supramolecular Complex [Co(H2O)6]·(Hnip)2·(H2nip)2·(DMA)2·(H2O)8 (nip=5-nitroisophthalate, DMA=CH3NHCH3)
Li-Qiong Wang
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorJin-Yu Guo
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorJian-Guo Zhang
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorLi Yang
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorXiao-Jing Qiao
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorRui-Feng Wu
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorWei Yu
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorLi-Qiong Wang
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorJin-Yu Guo
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorJian-Guo Zhang
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorLi Yang
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorXiao-Jing Qiao
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorRui-Feng Wu
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorWei Yu
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorAbstract
The crystal of [Co(H2O)6]·(Hnip)2·(H2nip)2·(DMA)2·(H2O)8 has been cultured using direct method and characterized by X-ray single crystal diffractometry, elemental analysis and FTIR spectroscopy. It crystallizes in triclinic system, P-1 space group with the cell parameters of a=0.7012(1) nm, b=1.1378(2) nm, c=1.6612(3) nm, α=84.92(3)°, β=85.19(3)°, γ=85.91(3)°, V=1.3128(5) nm3, Z=1, Dc1.573 g·cm−3. Final R indices [I>2σ(I)] are:R1=0.0279, wR2=0.0765 while R indices for all data are:R1=0.0327, wR2=0.0806. The Co coordination octahedra are each surrounded by two Hnip, two H2nip, two DMA and eight water molecules that are linked by hydrogen bonds and π-π stacking interactions. Thermal analyses of DSC and TG-DTG have been performed on the complex to predict its thermal decomposition mechanism and determine the most probable kinetic model function using Kissinger, Ozawa, integral and differential methods.
REFERENCES
- 1 Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R.. Angew. Chem., Int. Ed., 2004, 43, 1466.
- 2 Yaghi, O. M.; O'Keeffe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J.. Nature, 2003, 423, 705.
- 3 Eddaoudi, M.; Moler, D. B.; Li, H. L.; Chen, B. L.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M.. Acc. Chem. Res., 2001, 34, 319.
- 4 Zhang, X. F.; Huang, D. G.; Chen, C. N.; Liu, Q. T.; Liao, D. Z.; Li, L. C.. Inorg. Chem. Commun., 2005, 8, 22.
- 5 Konar, S.; Manna, S. C.; Zangrando, E.; Mallah, T.; Ribas, J.; Chaudhuri, N. R.. Eur. J. Inorg. Chem., 2004, 4202.
- 6 Long, L. S.; Chen, X. M.; Tong, M. L.; Sun, Z. G.; Ren, Y. P.; Huang, R. B.; Zheng, L. S.. J. Chem. Soc., Dalton Trans., 2001, 2888.
- 7 Ye, Q.; Chen, X. B.; Song, Y. M.; Wang, X. S.; Zhang, J.; Xiong, R. G.; Fun, H. K.; You, X. Z.. Inorg. Chim. Acta, 2005, 358, 1258.
- 8 Liu, S. G.; Liu, W.; Zuo, J. L.; Li, Y. Z.; You, X. Z.. Inorg. Chem. Commun., 2005, 8, 328.
- 9 Huang, H. M.; Wang, K. M.; Tan, W. H.; An, D. L.; Yang, X. H.; Huang, S. S.; Zhai, Q. G.; Zhou, L. J.; Jin, Y.. Angew. Chem., Int. Ed., 2004, 43, 5635.
- 10 Tao, J.; Yin, X.; Wei, Z. B.; Huang, R. B.; Zheng, L. S.. Eur. J. Inorg. Chem., 2004, 125.
- 11 Luo, J. H.; Hong, M. C.; Wang, R. H.; Cao, R.; Han, L.; Lin, Z. Z.. Eur. J. Inorg. Chem., 2003, 2705.
- 12 Rowsell, J. L. C.; Millward, A. R.; Park, K. S.; Yaghi, O. M.. J. Am. Chem. Soc., 2004, 126, 5666.
- 13 Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O'Keeffe, M.; Yaghi, O. M.. Science, 2003, 300, 1127.
- 14
Kondo, M.;
Okubo, T.;
Asami, A.;
Noro, S.;
Yoshitomi, T.;
Kitagawa, S.;
Ishii, T.;
Matsuzaka, H.;
Seki, K..
Angew. Chem., Int. Ed.,
1999,
38,
140.
10.1002/(SICI)1521-3773(19990115)38:1/2<140::AID-ANIE140>3.0.CO;2-9 CAS Web of Science® Google Scholar
- 15 Düren, T.; Sarkisov, L.; Yaghi, O. M.; Snurr, R. Q.. Langmuir, 2004, 20, 2683.
- 16 Pan, L.; Liu, H. M.; Lei, X. G.; Huang, X. Y.; Olson, D. H.; Turro, N. J.; Li, J.. Angew. Chem., Int. Ed., 2003, 42, 542.
- 17 Zhang, L. P.; Wan, Y. H.; Jin, L. P.. Polyhedron, 2003, 22, 981.
- 18 Eddaoudi, M.; Kim, J.; Wachter, J. B.; Chae, H. K.; O'Keeffe, M.; Yaghi, O. M.. J. Am. Chem. Soc., 2001, 123, 4368.
- 19 Zheng, C. G.; Chen, Z. F.; Zhang, J.; Xiong, R. G.; You, X. Z.. Inorg. Chem. Commun., 2001, 4, 165.
- 20
Chen, X. M.;
Liu, G. F..
Chem. Eur. J.,
2002,
8,
4811.
10.1002/1521-3765(20021018)8:20<4811::AID-CHEM4811>3.0.CO;2-R CAS PubMed Web of Science® Google Scholar
- 21
Hohn, F.;
Pantenburg, I.;
Ruschewitz, U..
Chem. Eur. J.,
2002,
8,
4536.
10.1002/1521-3765(20021004)8:19<4536::AID-CHEM4536>3.0.CO;2-I CAS PubMed Web of Science® Google Scholar
- 22 Burrows, A. D.; Donovan, A. S.; Harrington, R. W.; Mahon, M. F.. Eur. J. Inorg. Chem., 2004, 4686.
- 23 Kissinger, H. E.. Anal. Chem., 1957, 29, 1702.
- 24 Ozawa, T.. Bull. Chem. Soc. Jpn., 1965, 38, 1881.
- 25 Sheldrick, G. M.. Acta Crystallogr. Sect. A, 1990, 46, 467.
- 26 Sheldrick, G. M., SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Germany, 1997.
- 27 Nyquist, R. A.; Kagel, R. O., Infrared Spectra of Inorganic Compounds, Academic Press, New York, 1971, p. 218.
- 28 MacCallum, J. R.; Tanner, J.. Eur. Polym. J., 1968, 4, 333.
- 29 Satava, V.; Sestak, J.. Thermochim. Acta, 1971, 2, 423.
- 30 Agrawal, R. K.. J. Therm. Anal., 1987, 32, 149.
- 31 Hu, R. Z.; Yang, Z. Q.; Liang, Y. J.. Thermochim. Acta, 1988, 123, 135.
- 32a Sharp, J. H.; Wendworth, S. A.. Anal. Chem., 1969, 41, 2060.
- 32b Achar, B. N.; Brindley, G. W.; Sharp, J. H., Proceedings of International Clay Conference, Jerusalem, Israel, 1966, p. 67.
- 33a Phadnis, A. B.; Deshpande, V. V.. Thermochim. Acta, 1983, 62, 361.
- 33b Skvara, F.; Sestak, J. J.. Therm. Anal., 1975, 8, 477.
- 34 Zsako, J. J.. Therm. Anal., 1976, 9, 101.
