[H₂N(CH₂)₃NH₃]₂[MoO₂(C₁₀H₆O₂)₂] (1) was synthesized by the reaction of (n-Bu₄N)₄[Mo₈O₂₆] with 2,3-dihydroxynaphthalene in the mixed solvent of CH₃OH, CH₃CN and 1,3-propanediamine. (C₅H₁₁N₂)₂- [H₂N(CH₂)₃NH₂][MoO₂(C₁₀H₆O₂)₂] (2) was obtained by the reaction of Na₂MoO₄·2H₂O with 2,3-dihydroxy- naphthalene in the same solvent above. Both of the complexes possess complex anion [Mo(VI)O₂(OC₁₀H₆O)₂]²⁻ which shows pseudo-octahedrally coordinated fashion, while the counterions are two protonated 1,3-propanedia- mine in complex 1 and (C₅H₁₁N₂)⁺ in complex 2. (C₅H₁₁N₂)⁺ is the byproduct of reaction 2, which results from combination of acetonitrile with 1,3-propanediamine. Packing diagrams of the two complexes are also different. There is anti-parallel-aligned-double-meso-bilayer unit in complex 1. However there are four chiral anions arranged in anticlockwise orientation in complex 2.

REFERENCES

1 Suzuki, Y.; Terao, H.; Fujita, T.. Bull. Chem. Soc. Jpn., 2003, 76, 1493.
10.1246/bcsj.76.1493
CAS Web of Science® Google Scholar
2 Chen, Y.; Yekta, S.; Yudin, A. K.. Chem. Rev., 2003, 103, 3155.
10.1021/cr020025b
CAS PubMed Web of Science® Google Scholar
3 Beck, W.; Sunkel, K.. Chem. Rev., 1988, 88, 1405.
10.1021/cr00089a017
CAS Web of Science® Google Scholar
4 Schrock, R. R.; Hoveyda, A. H.. Angew. Chem., Int. Ed., 2003, 42, 4592.
10.1002/anie.200300576
CAS PubMed Web of Science® Google Scholar
5 Lu, X. M.; Zhong, R.; Liu, S. C.; Liu, Y.. Polyhedron, 1997, 16, 3865.
10.1016/S0277-5387(97)00165-4
CAS Web of Science® Google Scholar
6 Lu, X. M.; Zhu, H. J.; Liu, S. C.. Chin. J. Chem., 1994, 12, 67.
Google Scholar
7 Lu, X. M.; Jin, X. L.; Liu, S. C.. Chem. J. Chin. Univ., 1996, 17, 1173 (in Chinese).
CAS Web of Science® Google Scholar
8 Hroch, A.; Gemmecker, G.; Thiel, W. R.. Eur. J. Inorg. Chem., 2000, 5, 1107.
10.1002/(SICI)1099-0682(200005)2000:5<1107::AID-EJIC1107>3.0.CO;2-E
Google Scholar
9 Wong, Y. L.; Yang, Q. C.; Zhou, Z. Y.; Ng, D. K. P.. New J. Chem., 2001, 25, 353.
10.1039/b006979p
CAS Web of Science® Google Scholar
10 Sheldon, A.; Kochi, J. K., Metal-Catalyzed Oxidation of Organic Compounds, Academic Press, New York, 1981.
Google Scholar
11 Sato, K.; Aoki, M.; Takagi, J.; Zimmermann, K.; Noyori, R.. Bull. Chem. Soc. Jpn., 1999, 72, 2287.
10.1246/bcsj.72.2287
Web of Science® Google Scholar
12 Herrmann, W. A.; Fridgen, J.; Lobmaier, G. M.; Spiegler, M.. New J. Chem., 1999, 23, 5.
10.1039/a808343f
CAS Web of Science® Google Scholar
13 Herrmann, W. A.; Haider, J. J.; Fridgen, J.; Lobmaier, G. M.; Spiegler, M.. J. Organomet. Chem., 2000, 603, 69.
10.1016/S0022-328X(00)00112-1
CAS Web of Science® Google Scholar
14 Nakayama, Y.; Ikushima, N.; Ueyama, N.; Nakamura, A.; Harada, A.. Chem. Lett., 2000, 434.
10.1246/cl.2000.434
Web of Science® Google Scholar
15 Hagen, W. R.; Arendsen, A. F.. Struct. Bond., 1998, 90, 161.
10.1007/3-540-62888-6_6
CAS Web of Science® Google Scholar
16 Mitchell, J. M.; Finney, N. S.. J. Am. Chem. Soc., 2001, 123, 862.
10.1021/ja002697u
CAS PubMed Web of Science® Google Scholar
17 Trost, M. K.; Bergman, R. G.. Organometallics, 1991, 10, 1172.
10.1021/om00050a058
CAS Web of Science® Google Scholar
18 Belgacem, J.; Kress, J.; Osborn, J. A.. J. Am. Chem. Soc., 1992, 114, 1501.
10.1021/ja00030a067
CAS Web of Science® Google Scholar
19 Tucci, G. C.; Donahue, J. P.; Holm, R. H.. Inorg. Chem., 1998, 37, 1602.
10.1021/ic971426q
CAS Web of Science® Google Scholar
20 Schultz, B. E.; Gheller, S. F.; Scott, M. J.; Holm, R. H.. J. Am. Chem. Soc., 1993, 115, 2714.
10.1021/ja00060a021
CAS Web of Science® Google Scholar
21 Lu, X. M.; Liu, S. C.; Mao, X. A.. J. Mol. Struct., 2001, 562, 89.
10.1016/S0022-2860(00)00764-X
CAS Web of Science® Google Scholar
22 Lu, X. M.; Zhu, H. J.; Yuan, H. Z.. Spectroscopy and Spectral Analysis, 2002, 22, 36 (in Chinese).
CAS PubMed Web of Science® Google Scholar
23 Lu, X. M.; Lu, J. F.; Mao, X. A.. Chin. J. Chem., 2002, 20, 617.
10.1002/cjoc.20020200619
CAS Web of Science® Google Scholar
24 Lu, X. M.; Liu, S. C.; Mao, X. A.. Chin. Sci. Bull., 2002, 20, 617 (in Chinese).
10.1002/cjoc.20020200619
CAS Web of Science® Google Scholar
25 Lu, X. M.; Song, F. G.; Lou, F. Y.. Chin. J. Chem., 2003, 21, 1474.
10.1002/cjoc.20030211116
CAS Web of Science® Google Scholar
26 Lu, X. M.; Liu, S. C.; Jiang, J.. Chin. J. Chem., 2003, 21, 650.
CAS Web of Science® Google Scholar
27 Lu, X. M.; Deng, Y.; Li, L.. Chem. J. Chin. Univ., 2005, 26, 611 (in Chinese).
CAS Web of Science® Google Scholar
28 Lu, X. M.; Wang, B.; Song, F. G.; Wang, J.. J. Mol. Struct., 2006, 789, 18.
10.1016/j.molstruc.2005.12.011
CAS Web of Science® Google Scholar
29 The data were calculated by Chem Office 2004.
Google Scholar
30 Sadter standard carbon-13 NMR spectra 14471c, 29063c.
Google Scholar
31 Ren, C. X.; Ye, B. H.; Zhu, H. L.; Shi, J. X.; Chen, X. M.. Inorg. Chim. Acta, 2004, 357, 443.
10.1016/j.ica.2003.06.003
CAS Web of Science® Google Scholar
32 Zhang, J. P.; Lin, Y. Y.; Huang, X. C.; Chen, X. M.. J. Am. Chem. Soc., 2005, 127, 5495.
10.1021/ja042222t
CAS PubMed Web of Science® Google Scholar

Citing Literature

Volume25, Issue4

April, 2007

Pages 448-452

The Reaction of Molybdenum with 2,3-Dihydroxynaphthalene

Abstract

REFERENCES

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

The Reaction of Molybdenum with 2,3-Dihydroxynaphthalene

Abstract

REFERENCES

Citing Literature

References

Related

Information