Formation, isolation and characterization of a new ruthenium complex in reaction of acetone masked terminal alkynone with transfer hydrogenation catalyst
Min-Jie Guo
State Key Laboratory of Organometallics, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Search for more papers by this authorDao Li
State Key Laboratory of Organometallics, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Search for more papers by this authorYan-Hui Sun
Department of Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorJiang Cheng
Department of Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorCorresponding Author
Zhao-Guo Zhang
State Key Laboratory of Organometallics, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Tel.: +8621-54925149: Fax: + 8621-64166128Search for more papers by this authorMin-Jie Guo
State Key Laboratory of Organometallics, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Search for more papers by this authorDao Li
State Key Laboratory of Organometallics, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Search for more papers by this authorYan-Hui Sun
Department of Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorJiang Cheng
Department of Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorCorresponding Author
Zhao-Guo Zhang
State Key Laboratory of Organometallics, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Tel.: +8621-54925149: Fax: + 8621-64166128Search for more papers by this authorAbstract
Reaction of [1S,2S-(Ts-diphen)Ru(II)(p-cymene)] (1S,2S-Ts-diphen = 1S,2S-N-tosyl-l,2-diphenylethylenediamine) and 2-hydroxy-2-methyl-non-3-yn-5-one under transfer hydrogenation condition gave a ruthenium complex bearing a 2,5-dihydrofuran moiety. The complex was characterized and a possible mechanism for the formation of the complex was proposed.
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