Volume 22, Issue 11 pp. 1231-1234

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Electrolytic fixation of CO₂ by electrocarboxylation of rx on nanocrystalline TiO₂-Pt cathode

Dao-Bao Chu,

Dao-Bao Chu

[email protected]

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

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Xiao-Hua Li,

Xiao-Hua Li

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

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Xin-Yuan Liu,

Xin-Yuan Liu

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

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Wen-Li Yao,

Wen-Li Yao

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

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Dao-Bao Chu,

Dao-Bao Chu

[email protected]

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

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Xiao-Hua Li,

Xiao-Hua Li

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

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Xin-Yuan Liu,

Xin-Yuan Liu

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

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Wen-Li Yao,

Wen-Li Yao

College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China

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First published: 26 August 2010

https://doi.org/10.1002/cjoc.20040221104

Citations: 13

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Abstract

Electrolytic fixation of CO₂ was investigated by electrocarboxylation of organic halides (a), and four esters (I, II, III, IV) were obtained in moderate yields. Electrochemical reduction esterifications of RX in the presence of CO₂ were carried out on nanocrystalline TiO₂-Pt electrode. The electrochemical behavior of RX in the presence of CO₂ was investigated by the technique of cyclic voltammetry, and the probable reaction mechanism was proposed.

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Volume22, Issue11

November 2004

Pages 1231-1234

Electrolytic fixation of CO₂ by electrocarboxylation of rx on nanocrystalline TiO₂-Pt cathode

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Electrolytic fixation of CO₂ by electrocarboxylation of rx on nanocrystalline TiO₂-Pt cathode