Bismuth(III) Complexes with N,N-Di(2-hydroxylethyl)aminodithiocarboxylate: Synthesis and Crystal Structure of {Bi[S2CN(C2H4OH)2]2[1, 10-Phen]2(NO3)}·3H2O and (Bi[S2CN(C2H4OH)2]3}2
Abstract
Two novel one- and two-dimensional network structure bismuth(III) complexes with N, N-di(2-hydroxylethyl)-aminodithiocarboxylate, {Bi[S2CN(C2H4OH)2]2[1, 10-Phen]2(NO3)}·3H2O (1) and (Bi[S2CN(C2H4OH)2]3)2 (2) were synthesized. Their crystal and molecular structures were determined by X-ray single crystal diffraction analysis. The crystal 1 belongs to monoclinic system with space group C2/c, a=1.6431(7) nm, b=2.4323(10) nm, c= 1.2646(5) nm, β=126. 237(5), Z=4, V=4.076(3) nm3, Dc=1.757 Mg/m3, μ=4.598 mm−1, F(000)=2156, R= 0.0211, wR=0.0369. The structure shows a distorted square antiprism configuration with eight-coordination for the central Bi atom. The one-dimensional chain structure was formed by H-bonding interaction between hydroxyl group of N, N-di(2-hydroxylethyl)aminodithiocarboxylate ligands and crystal water. The crystal 2 belongs to monoclinic system with space group p2(1)/c, a= 1.1149(4) nm, b=2.1274(8) nrn, c=2.2107(8) nm, β=98.325(8)°, 2=4, V=5. 188(3) nm3, Dc=1.920 Mg/m3, μ=7.315 mm−1, F(000)=2944, R=0.0565, wR=0.0772. The structure shows a distorted square antiprism configuration with eight-coordination for the central Bi atoms. The two-dimensional network structure was formed by H-bonding interaction between adjacent molecules.
