The synthesis and characterization of novel Schiff base liquid crystalline crown ethers prepared from the intermediates 4-(4′-alkoxylbiphenyl-4-carbonyl) benzaldehyde, cis- and trans-4,4′-diaminodibenzo-18-crown-6 are described. The structure of these compounds have been well characterized by elemental analysis, IR, ¹H NMR and MS spectroscopy. The liquid-crystalline behavior of these compounds was also investigated by differential scanning calorimetry (DSC), polarizing optical microscopy (POM) with a heating stage and polarimetric analysis.

References

1 Lehn, J. M. Angew. Chem, Int. Ed. Engl. 1988, 27, 89.
10.1002/anie.198800891
Web of Science® Google Scholar
2 Shinkai, S.; Nishi T.; Mastsude T. Chem Lett. 1991, 437.
Google Scholar
3 Zhu, Y. M.; Wei, Y.; Hu, Z. L. Phys. Lett. A 1994, 188, 287.
10.1016/0375-9601(94)90452-9
CAS Web of Science® Google Scholar
4 Bogatskaya, L. G.; Lukyanenko, N. G.; Kulygine, E. Y.; Nesterenko, N. L. The Ninth International Conference on Liquid Crystals, Programme and Abstracts, Bangalore, 1982, p. 15.
Google Scholar
5 He, G. X.; Wada, F.; Kikukawa, K.; Shinkai, S.; Matsuda, T. J. Org. Chem. 1990, 55, 541.
10.1021/jo00289a028
CAS Web of Science® Google Scholar
6 Liebmann, A.; Mertesdorf, C.; Plesnivy, T.; Ringsdorf, H.; Wendorff, J. H. Angew. Chem., Int. Ed. 1991, 30, 1375.
10.1002/anie.199113751
Web of Science® Google Scholar
7 Idziak, S. H. J.; Maliszewsky, N. C.; Heiney, P. A.; McCauly, J. P.; Sprengeler, J. P. A.; Smith, A. B. J. Am Chem. Soc. 1991, 113, 7666
10.1021/ja00020a031
CAS Web of Science® Google Scholar
8 Li, L. Z.; Zhu, J. L.; Zhao, W.; Xie, M. G.; Jiang, Q. Chem J. Chin. Univ. 1998, 19, 1422 (in Chinese).
CAS Web of Science® Google Scholar
9 Wu, Y. J.; Zhao, B.; Zhao, L. W. Chin. J. Chem. 1993, 11, 360.
10.1002/cjoc.19930110410
CAS Google Scholar
10 Xie, M. G.; Peng, M. S.; Jiang, Q.; Hu, Z. L. Wang, X. J. Liq. Cryst. 1996, 21, 461.
10.1080/02678299608032855
CAS Web of Science® Google Scholar
11 Penin, D. D.; Armango, W. L. F.; Penin, D. R. Purification of Laboratory Chemicals, 2nd. ed., Pergamon Ress, 1980, Translated by Shi, Y., Chemical Industrial Press, Beijing, 1987, p. 155; p. 291; p. 312; p. 346; p. 408.
Google Scholar
12 He, K. K.; Bang, X. J.; Li, Z. F.; Zhang, S. Y.; Zheng, S. J.; Yang, Z. H.; Guo, K.; Zhou, Q. F. Chem. J. Chin. Unvi. 2002, 23, 2000 (in Chinese).
CAS Web of Science® Google Scholar
13 Zhou, Q. F. Advances in Liquid Crystalline Polymers and Supramolecules. Huazhong University of Science and Technology Press, Wuhan, 2002, pp. 44–48 (in Chinese).
Google Scholar
14 Li, F.; Ning, C. F.; Zheng, S. J.; Zhang, S. Y.; Cao, S. K. Marcromolecules 1999, 32, 7040.
10.1021/ma981931m
CAS Web of Science® Google Scholar

Citing Literature

Volume22, Issue4

April 2004

Pages 395-399

Synthesis of Schiff Base-type Liquid Crystalline Crown Ethers Containing Dibenzo-18-Crown-6 Unit

Abstract

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Synthesis of Schiff Base-type Liquid Crystalline Crown Ethers Containing Dibenzo-18-Crown-6 Unit

Abstract

References

Citing Literature

References

Related

Information