Preparation and Characterization of TiO2-pillared Layered HNb3O8
Xian-Ji Guo
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorWen-Hua Hou
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorYan Kong
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorWei-Ping Ding
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorYi-Ning Fan
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorTian-Yang Yao
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorQi-Jie Yan
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorYi Chen
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorXian-Ji Guo
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorWen-Hua Hou
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorYan Kong
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorWei-Ping Ding
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorYi-Ning Fan
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorTian-Yang Yao
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorQi-Jie Yan
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorYi Chen
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorAbstract
Oligomeric titanium(IV) cation ([Ti(OH)x(H2O)y]&z−;)-intercalated niobate was prepared through a stepwise ion-exchange mute, in which n-decylamine was employed as a preswelling agent and titanium isopropoxide as titanium source. Titania-pillared layered niobic acid was then obtained by calcining oligomeric titanium(IV) cation-intercalated niobate at 450 °C in air. Characterization of this pillared material indicated that the material had a porous layered structure with an interlayer distance of 1.38 nm and a BET (Brunauer-Emmett-Teller) surface area of 34 m2·g−1. The layered structure was still retained after the pillared material was heated at 550 T.
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