Article

Full Access

Hydrothermal Synthesis and Properties of Open-Framework Mixed-valence Iron Phosphates Fe₂^lll Fe^ll_1.5(PO₄)₃ with Three-dimensional Structure

Li-Ying Duan

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

Fu-Chen Liu,

Fu-Chen Liu

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

En-Bo Wang,

En-Bo Wang

[email protected]

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Search for more papers by this author

Yang-Guang Li,

Yang-Guang Li

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

Chang-Wen Hu,

Chang-Wen Hu

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

Lin Xu,

Lin Xu

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

Li-Ying Duan,

Li-Ying Duan

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

Fu-Chen Liu,

Fu-Chen Liu

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

En-Bo Wang,

En-Bo Wang

[email protected]

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Search for more papers by this author

Yang-Guang Li,

Yang-Guang Li

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

Chang-Wen Hu,

Chang-Wen Hu

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

Lin Xu,

Lin Xu

Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

Search for more papers by this author

First published: 26 August 2010

https://doi.org/10.1002/cjoc.20040220113

Citations: 3

About

PDF

Tools

Share a link

Email
Wechat
Bluesky

Abstract

The open-framework iron phosphate Fe₂^lllFe_1.5^ll,(PO₄)₃ was hydrothermally synthesized and characterized by elemental analysis, IR, EPR, XPS and single crystal X-ray diffraction analysis. The title compound crystallized in the triclinic, space group P1 with a=0.64724(4) nm, b=0.79651(6) nm, c=0.94229(5) nm, a= 104.447(2)°. β= 108.919(4)°. y= 101.741(4)°, V=0.42302(5) nm³, Z= 1 and R_I (wR₂)=0.0307 (0.0793). Crystal data were collected on a Rigaku R-AXIS RAPID IP diffractometer with Mo Ka (γ=0.071073 nm) at 293(2) K in the range of 2.43°<Õ <27.46°. The structure of 1 consists of 19 non-hydrogen atoms including three and a half crystallographically independent Fe and three P atoms. Fe(1) connects its symmetrical Fe(1A) through bridging oxygen forming a dimer and the dimers are connected by Fe(4) forming an infinite staircase-like chain. Fe(2) and Fe(3) connect the infinite chains into a layer with bridging oxygen. Layers are interconnected via Fe(4) forming the six-membered and eight-membered channel systems.

References

1 Ai, M. Appl. Catal. A 2002, 234, 235.
10.1016/S0926-860X(02)00229-6
CAS Web of Science® Google Scholar
2 Ai, M. Appl. Cotal. A 2002, 232, 1.
10.1016/S0926-860X(02)00097-2
CAS Web of Science® Google Scholar
3 Zarestky, J. L.; Vaknin, D.; Chakoumakos, B. C. J. Magn Magn Mater: 2001, 234, 401.
10.1016/S0304-8853(01)00425-5
CAS Web of Science® Google Scholar
4 Xu, L.; Wang, E.-B.; Li, Z. New J. Chem. 2002, 782.
Google Scholar
5 Chang, J. S.; Park, S. E.; Gao, Q. M. Chem. Commun. 2001, 9, 859.
10.1039/b009160j
CAS Web of Science® Google Scholar
6 Sassoye, C. T.; Loiseau, F.; Taulelle, C. Chem Commun. 2000, 943.
Google Scholar
7 Hsu, K.-F.; Wang, S.-L. Chem. Commun 2000, 135.
Google Scholar
8 Natarajan, S.; Anfeld, M. P.; Cheetham, A. K. Angew. Chem, Int. Ed Engl. 1997, 36, 978.
10.1002/anie.199709781
CAS Web of Science® Google Scholar
9 Stock, N.; Stucky, G. D.; Cheetham, A. K. Chem Commun 2000, 2277.
Google Scholar
10 Yuan, M.; Li, Y.-G.; Wang, E.-B. J. Chem Soc., Dalton Trans. 2002, 2916.
Google Scholar
11 Neeraj, S.; Noy, M. L.; Cheetham, A. K. J. Solid State Chem 2003, in press.
Google Scholar
12 Guillou, N.; Gao, Q.; Forster, P. M. Angew. Chem, Int. Ed. 2001, 40, 4745.
10.1002/1521-3773(20011217)40:24<4745::AID-ANIE4745>3.0.CO;2-5
CAS PubMed Web of Science® Google Scholar
13 Choudhary, A.; Natarajan, S.; Rao, C. N. R. J. Solid State Chem 1999, 146, 538.
10.1006/jssc.1999.8428
Web of Science® Google Scholar
14 Neeraj, S.; Natarajan, S.; Rao, C. N. R. Chem Commun. 1999, 165.
Google Scholar
15 Lu, Y.; Wag, E.-B.; Yuan, M. J. Chem Soc., Dalton Trans. 2002, 3029.
Google Scholar
16 Riou-Cavellec, M.; Sanselme, M.; Grenéche, J. M. Solid StateSci. 2000, 2, 717.
10.1016/S1293-2558(00)01080-3
CAS Web of Science® Google Scholar
17 Lii, K.-H.; Huang, Y.-F. Chem Commun. 1997, 1311.
Google Scholar
18 Lii, K-H.; Huang, Y.-F. Chem Commun. 1997, 939.
Google Scholar
19 Mahesh, S.; Mark Green, A.; Natarajan, S. J. Solid State Chem. 2002, 165, 334.
10.1006/jssc.2002.9547
CAS Web of Science® Google Scholar
20 Choudhury, A.; Natarajan, S. J. Mater. Chem 1999, 9, 3113.
10.1039/a906663b
CAS Web of Science® Google Scholar
21 Boudin, S.; Lii, K.-H. Inorg. Chem. 1998, 37, 799.
10.1021/ic970655+
CAS Web of Science® Google Scholar
22 Sheldrick, G. M. SHELXS 97. Program for Crystal Structure Solution, University of Göttingen, 1997.
Google Scholar
23 Sheldrick, G. M. SHELXS 97, Program for Crystal Structure, Refinement, University of Göttingen, 1997.
Google Scholar
24 Brown, I. D.; Altermatt, D. Acta Crysallogr. 1985, B41, 244.
10.1107/S0108768185002063
CAS Google Scholar
25 Nefedov, V. I.; Salyn, Y. V.; Leonhardt, G.; Scheibe, R. J. Electron Spectrosc. Relat. Phenom 1977, 10, 121.
10.1016/0368-2048(77)85010-X
CAS Web of Science® Google Scholar
26 Nemoshalenko, V. V.; Didyk, V. V.; Krivitskii, V. P.; Senekevich, A. I. Zh. Neorg. Khim 1983, 28, 2182.
Google Scholar

Citing Literature

Volume22, Issue1

January 2004

Pages 55-59

Hydrothermal Synthesis and Properties of Open-Framework Mixed-valence Iron Phosphates Fe₂^lll Fe^ll_1.5(PO₄)₃ with Three-dimensional Structure

Abstract

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Hydrothermal Synthesis and Properties of Open-Framework Mixed-valence Iron Phosphates Fe2lll Fell1.5(PO4)3 with Three-dimensional Structure

Abstract

References

Citing Literature

References

Related

Information

Hydrothermal Synthesis and Properties of Open-Framework Mixed-valence Iron Phosphates Fe₂^lll Fe^ll_1.5(PO₄)₃ with Three-dimensional Structure