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Synthesis and Structure of Tetraploid (Imidazole) Copper (II) Terephthalate, [Cu(Im)₄] (teph)

Jun Wan

College of Chemistry and Molecule Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

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Su-Juan Ye,

Su-Juan Ye

College of Chemistry and Molecule Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

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Yong-Hong Wen,

Yong-Hong Wen

College of Chemistry and Molecule Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

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Shu-Sheng Zhang,

Shu-Sheng Zhang

[email protected]

College of Chemistry and Molecule Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

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Jun Wan,

Jun Wan

College of Chemistry and Molecule Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

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Su-Juan Ye,

Su-Juan Ye

College of Chemistry and Molecule Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

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Yong-Hong Wen,

Yong-Hong Wen

College of Chemistry and Molecule Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

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Shu-Sheng Zhang,

Shu-Sheng Zhang

[email protected]

College of Chemistry and Molecule Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

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First published: 26 August 2010

https://doi.org/10.1002/cjoc.20030211112

Citations: 5

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Abstract

The crystal structure of [Cu (Im)₄] (teph) (Im = imidazole, teph = terephthalate) has been determined by X-ray crystallography. It crystallizes in the triclinic system, space group Pī with cell dimensions of a = 0.80356 (16) nm, b = 0.84269 (17) run, c = 0.88967 (18) nm, α = 76.90 (3)°, β = 68.95 (3)°, γ = 75.94 (3)°, and Z = 1. Its structure of the title compound is composed of discrete monomelic molecule of [Cu (Im)₄]-(teph). The copper (II) ions have a square plane geometry with the CuN₄ chromophore.

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Volume21, Issue11

November 2003

Pages 1458-1460

Synthesis and Structure of Tetraploid (Imidazole) Copper (II) Terephthalate, [Cu(Im)₄] (teph)

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Synthesis and Structure of Tetraploid (Imidazole) Copper (II) Terephthalate, [Cu(Im)₄] (teph)