A new tetra-N-substituted tetraazacrown ether derivative, 4,7, 13,16-tetra (2-cyanobenzyl)-1, 10-dioxa-4,7,13,16-tetraazacyclooctadecane, C₄₄H₄₈N₈O₂, has been synthesized and structurally characterized. It crystallizes in the monoclinic system, space group P2₁/c with a = 1.1176(3) nm, b =2.1906(7) nm, c = 0.8430(3) nm, V = 2.0132(10) nm³, β = 102.740(5)°, Z =4, D_c = 1.189 g/cm³, final R₁, = 0.0460, wR₂ = 0.0803. The liquid membrane transports of alkali metal cations using the new macrocycle as the ion-carrier were also studied. Compared with some macrocyclic ligands, our newly synthesized lig-and showed a good selectivity ratio for Na⁺/Li⁺.

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Volume21, Issue9

September 2003

Pages 1178-1182

Synthesis and crystal structure of a new armed-tetraazacrown ether and its liquid membrane transport of alkali metal cations

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Synthesis and crystal structure of a new armed-tetraazacrown ether and its liquid membrane transport of alkali metal cations

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