Volume 21, Issue 7 pp. 921-925

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Synthesis and Characterization of a Novel Perfluorinated Ionomer Polymer Containing Sulfonimide Functionality^†

Shi-Zheng Zhu,

Shi-Zheng Zhu

[email protected]

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Yun-Xiang Zhang,

Yun-Xiang Zhang

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Gui-Fang Jin,

Gui-Fang Jin

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Darryl D. Desmarteau,

Darryl D. Desmarteau

[email protected]

Department of Chemistry, H. L. Hunter Chemistry Laboratory Clemson University, Clemson, SC 29634–1905

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Shi-Zheng Zhu,

Shi-Zheng Zhu

[email protected]

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Yun-Xiang Zhang,

Yun-Xiang Zhang

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Gui-Fang Jin,

Gui-Fang Jin

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Darryl D. Desmarteau,

Darryl D. Desmarteau

[email protected]

Department of Chemistry, H. L. Hunter Chemistry Laboratory Clemson University, Clemson, SC 29634–1905

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First published: 26 August 2010

https://doi.org/10.1002/cjoc.20030210740

^†

Dedicated to Professor ZHOU Wei-Shan on the occasion of his 80th birthday.

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Abstract

The novel perfluorinated vinyl ether containing sulfonimide functionality CF₂ = CFOR₁SO₂NHSO₂CF₃ was synthesized by multiple reaction steps. It could be copolymerized with tetrafluoroethylene by radox initiator to give a novel perfluorinated ionomer polymer. Its physical and chemical properties were studied.

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Volume21, Issue7

July 2003

Pages 921-925

Synthesis and Characterization of a Novel Perfluorinated Ionomer Polymer Containing Sulfonimide Functionality^†

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Synthesis and Characterization of a Novel Perfluorinated Ionomer Polymer Containing Sulfonimide Functionality†

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Synthesis and Characterization of a Novel Perfluorinated Ionomer Polymer Containing Sulfonimide Functionality^†