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Self-assembly of Novel Hetero[3]rotaxane, [2]Rotaxanes and [2]Catenane^†

Wei-Xing Zhang

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Cui-Qin Fan,

Cui-Qin Fan

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Bo Tu,

Bo Tu

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Xin Zhao,

Xin Zhao

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Xi-Kui Jiang,

Xi-Kui Jiang

[email protected]

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Zhan-Ting Li,

Zhan-Ting Li

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Wei-Xing Zhang,

Wei-Xing Zhang

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Cui-Qin Fan,

Cui-Qin Fan

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Bo Tu,

Bo Tu

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Xin Zhao,

Xin Zhao

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Xi-Kui Jiang,

Xi-Kui Jiang

[email protected]

College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China Department of Chemistry, Fudan University, Shanghai 200433, China

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Zhan-Ting Li,

Zhan-Ting Li

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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First published: 26 August 2010

https://doi.org/10.1002/cjoc.20030210707

Citations: 10

^†

Dedicated to Professor ZHOU Wei-Shan on the occasion of his 80th birthday.

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Abstract

One linear template 13 and one cyclophane template 15, both incorporating two electron rich 1,4-dialkoxybenzene units and one diamide unit, have been synthesized. By utilizing donor-acceptor interaction and/or intermolecular hydrogen bonding assembling principles, one novel hetero[3]rotazane 22·4Cl, possessing one neutral and one tetracationic ring components, has been synthesized from 13, through neutral [2]rotaxane 21 as intermediate. With 15 as template, tetracationic [2]catenane 23·4PF₆ was assembled by using donor-acceptor interaction, but no neutral [2]rotaxane could be obtained under the typical conditions of hydrogen bonding assembling principle. The interlocked supramolecular compounds have been characterized and their spectral properties are investigated.

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Volume21, Issue7

July 2003

Pages 739-745

Self-assembly of Novel Hetero[3]rotaxane, [2]Rotaxanes and [2]Catenane^†

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Self-assembly of Novel Hetero[3]rotaxane, [2]Rotaxanes and [2]Catenane†

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Self-assembly of Novel Hetero[3]rotaxane, [2]Rotaxanes and [2]Catenane^†