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A Novel Three-dimensional Framework with Tunnels Based on the Cobalt-containing Molybdenum Phosphate Moieties

Huang Ru-Dan

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

School of Chemical Engineering & Materials Science, Beijing Institute of Technology, Beijing 100081, China

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Liu Fu-Chen,

Liu Fu-Chen

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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Li Yang-Guang,

Li Yang-Guang

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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Yuan Mei,

Yuan Mei

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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Wang En-Bo,

Wang En-Bo

[email protected]

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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De Ge-Ji-Hu,

De Ge-Ji-Hu

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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Huang Ru-Dan,

Huang Ru-Dan

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

School of Chemical Engineering & Materials Science, Beijing Institute of Technology, Beijing 100081, China

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Liu Fu-Chen,

Liu Fu-Chen

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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Li Yang-Guang,

Li Yang-Guang

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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Yuan Mei,

Yuan Mei

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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Wang En-Bo,

Wang En-Bo

[email protected]

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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De Ge-Ji-Hu,

De Ge-Ji-Hu

Institute of polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

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First published: 26 August 2010

https://doi.org/10.1002/cjoc.20030210509

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Abstract

A novel compound (H₂en)₅[CoMo₁₂O₅₀P₈(OH)₁₂] ·2H₂O (1) (en = H₂NCH₂CH₂NH₂) has been hydrothermally synthesized and characterized by elemental analyses, IR, EPR, XPS spectra and single-crystal X-ray diffraction analyses. Compound 1 crystallizes in a triclinic system, space group Pi, with a = 1.1863(2) nm, b = 1.3361(3) nm, c = 1.3783(3) nm, a = 88.13(3)°, β = 70.09(3)°, γ = 65.24(3)°, V = 1.8497(6) mn³, and R = 0.0417. The basic building blocks of compound 1 are|Mo₆P₄ [clusters forming dimers through the|CoO₆] octahedra. Compound 1 exhibits an unusual three-dimensional framework with tunnels owing to the extensive hydrogen bonding interactions between the dimers and H₂en.

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Volume21, Issue5

May 2003

Pages 515-519

A Novel Three-dimensional Framework with Tunnels Based on the Cobalt-containing Molybdenum Phosphate Moieties

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A Novel Three-dimensional Framework with Tunnels Based on the Cobalt-containing Molybdenum Phosphate Moieties

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