Synthesis and Crystal Structure of a Novel Hydrogen-Bonded Three-Dimensional Polymer [Zn (1,4-benzenedicarboxylate) -(pyridine)·H2O]n
Rui-Hu Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorMao-Chun Hong
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorJia-Bao Weng
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorRong Cao
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorJun-Hua Luo
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorRui-Hu Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorMao-Chun Hong
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorJia-Bao Weng
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorRong Cao
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorJun-Hua Luo
State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorAbstract
A zinc(II) complex [Zn(bdc)(py)·H2O]a (bdc=1,4-benzenedicarboxylate, py=pyridine) has been prepared and characterized. Single crystal X-ray diffraction analysis reveals that the complex crystallizes in the monoclinic space group P21/n with a = 0.84823(3), b = 0.91440(3), c = 1.65141(2) ran, β = 91.243(2)°, V= 1.28057(6) nm3, Z = 4. The coordination geometry at each Zn(II) center is a distorted tetrahedron. Two independent bdc ligands in a herringbone pattern link alternatively four-coordinated Zn(II) centers into a one-dimensional polymeric chain. Hydrogen bonds among coordinated water molecules and uncoordinated oxygen atoms of two independent bdc ligands from different polymeric chains extend one-dimensional polymeric chains into a three-dimensional structure.
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