Synthesis of a Tweezer-like Bis(phenylthiapropoxy)calix[4]-arene as a Cation/π Enhanced Sensor for Ion-Selective Electrodes
Hao Sun
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Department of Chemistry, Tianjin University, Tianjin 300072, China
Search for more papers by this authorXian-Shun Zeng
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorJian-Quan Liu
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorXue-Bing Leng
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorChen Qi-Fa
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorFeng-Bo Xu
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorQing-Shan Li
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorXi-Wen He
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorWen-Qin Zhang
Department of Chemistry, Tianjin University, Tianjin 300072, China
Search for more papers by this authorZheng-Zhi Zhang
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorHao Sun
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Department of Chemistry, Tianjin University, Tianjin 300072, China
Search for more papers by this authorXian-Shun Zeng
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorJian-Quan Liu
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorXue-Bing Leng
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorChen Qi-Fa
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorFeng-Bo Xu
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorQing-Shan Li
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorXi-Wen He
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorWen-Qin Zhang
Department of Chemistry, Tianjin University, Tianjin 300072, China
Search for more papers by this authorZheng-Zhi Zhang
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorAbstract
Two novel 25,27-dihydroxy-26,28-bis(3-phenyilhiapropoxy)-calix[4]arene (3) and 25,27-dihydroxy-26,28-bis(3-phenylthiapropoxy)-5,11, 17, 23-tetra-tert-butylcalix[4]arene (4) were synthesized for the evaluation of their ion-selectivity in ion-selective electrodes (ISEs). ISEs based on 3 and 4 as neutral ionophores were prepared, and their selectivity coefficients for Ag+ (lg Apotag,M) were investigated against other alkali metal, alkaline-earth metal, aluminum, thallium (I), lead and some transition metal ions using the separate solution method (SSM). These ISEs showed excellent Ag+ selectivity over most of the interfering cations examined, except for Hg2+ and Fe2+ having relative smaller interference (Ig Kpotag,M≤ − 2.1).
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