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Formation and Molecular Structure of an Ion Pair Iron (II) Compound Derived from 2,6-Bis- [1-(2,6-dibromophenylimino) -ethyl] pyridine and 2-Acetyl-6-[1-(2, 6-dibromophenylimino)-ethyl] pyridine

Rui-Fang Chen

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Chang-Tao Qian,

Chang-Tao Qian

[email protected]

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Jie Sun,

Jie Sun

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Rui-Fang Chen,

Rui-Fang Chen

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Chang-Tao Qian,

Chang-Tao Qian

[email protected]

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Jie Sun,

Jie Sun

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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First published: 26 August 2010

https://doi.org/10.1002/cjoc.20010190911

Citations: 6

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Abstract

Two novel tridentate ligands of 2,6-bis-[l-(2,6-dibromophenylimino) ethyl] pyridine (L₁) and2-acetyl-6-[1-(2,6-dibromophenylimino) ethyl] pyridine (L2) have been synthesized. The iron(II) complex of L₁ and L₂ has been characterized with the crystal structure of [Fe(L₁)(L₂)]²⁺ [FeCl₄]² CH₂Cl₂ [monoclinic, P2₁ (#11), a = 1.0562(4), b = 2.0928(4), c = 1.2914(2) nm, β = 100.12°, V = 2.810(1) nm³ D_c = 1.879 g/cm³ and Z = 2].

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Volume19, Issue9

September 2001

Pages 866-869

Formation and Molecular Structure of an Ion Pair Iron (II) Compound Derived from 2,6-Bis- [1-(2,6-dibromophenylimino) -ethyl] pyridine and 2-Acetyl-6-[1-(2, 6-dibromophenylimino)-ethyl] pyridine

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Formation and Molecular Structure of an Ion Pair Iron (II) Compound Derived from 2,6-Bis- [1-(2,6-dibromophenylimino) -ethyl] pyridine and 2-Acetyl-6-[1-(2, 6-dibromophenylimino)-ethyl] pyridine

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