Crystal Structure and Luminescence of [Eu(TTA)3·DAF]·0.5C7H8 Complex Excited by Visible Light
Hul-Biao Liu
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorBao-Long Li
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorHua-Qin Wang
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorZheng Xu
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorHul-Biao Liu
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorBao-Long Li
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorHua-Qin Wang
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorZheng Xu
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorAbstract
The non-ionic europium(III) complex [Eu(TTA)3·DAF]·0.5C7H8 (TTA = 2-thenoytrifluoroacetonate, DAF = 4, 5-diazafluoren-9-one) was synthesized. The structural determination has been carried out. DAF coordination induces the both excitation spectra in the solid state and solution having a red shift and sensitizes Eu3+ luminescence under visible light excitation.
References
- 1(a) Sabbatini, N; Guardigli, M; Lehn, J. M., Coord. Chem. Rev. 1993, 123, 201. (b) Piguet, C; Bunzli, J. C. G.; Bemardinelli, C; Hopfgartner, C; Petoud, S; Schaad, O., J. Am. Chem. Soc. 1996, 118, 6681. (c) Piguet, C; Bunzli, J. C. G.; Bemardinelli, G; Hopfgaitner, G; Williams, A. F., J. Am. Chem. Soc. 1993, 115, 8197.
- 2 Gueniero, P; Tamburini, S; Vigato, P. A., Coord. Chan. Rev. 1995, 139, 17.
- 3 Elbanowski, M; Makowslca, B., J. Photochem. Photobiol. A. 1995, 99, 85.
- 4 Parker, D; Williams, J. A. G., J. Chem. Soc., Dalton Trans. 1996, 3613.
- 5 Weissman, S. L., J. Chem. Phys. 1942, 10, 214.
- 6 Steemers, F. J.; Verboom, W; Reinhoudt, D. N.; van der Tol, E. B.; Verhoeven, J. W., J. Am. Chem. Soc. 1995, 117, 9408.
- 7 Martinus, H. V. W.; Marcel, A. D.; Johannes, W. H.; Jan, W. V., Chem. Commun. 1999, 799.
- 8 Henderson, L. J.; Fronczek, F. R. Jr.; Cherry, W. R., J. Am. Chem. Soc. 1984, 106, 5876.
- 9 Charles, R. G.; Ohlmann, R. C., J. Inorg. Nucl. Chem. 1965, 27, 255.
- 10 Nakamaru, K., Bull. Chem. Soc. Jpn. 1982, 55, 2697.
- 11 Credi, A; Prodi, L., Spectrochim. Acta A 1998, 54, 159.
- 12(a) Sheldrick, G. M., SXCANS (Version 2.1), Siemens Analytical X-Ray Instruments Inc., Madison, USA, 1994. (b) Sheldrick, G. M., SHELXTL (Version 5.0), Siemens Industrial Autamation Inc., Analytical Instrumentation, USA, 1995.
- 13 Sheldrick, G. M., SHELXTL Reference Manual, Version 5.03, Siemens Energy and Automatic Inc., Analytical Instrumentation, Madison, W1, 1996.
- 14 Su, C. Y.; Kang, B. S.; Liu, H. Q.; Wang, Q. G.; Chen, Z. N.; Lu, Z. L.; Tong, Y. X.; Mak, T. C. W., Inorg. Chem. 1999, 38, 1374.
- 15 Melby, L. R.; Rose, N. J.; Abramson, E; Cans, J. C., J. Am. Chem. Soc. 1964, 86, 5117.
- 16 Jiang, W; Wang, K. Z.; Huang, C. H.; Xu, G. X., J. Rare Earths 1995, 13, 241.
- 17 Wang, K. Z.; Gao, L. H.; Huang, C. H.; Yao, G. Q.; Zhao, X. S.; Xia, X. H.; Xu, J. M.; Li, T. K., Solid State Commun. 1996, 98, 1075.
- 18 Huang, C. H., Coordination Chemistry of Rare Earth Element, Science Publishing Co., Perking, 1997, p. 234.
- 19 Crosby, G. A.; Whan, R. E.; Alire, R. M., J. Chem. Phys. 1961, 34, 743.
- 20 Sager, W. F.; Fillipescu, N; Serafin, F. A., J. Phys. Chem. 1965, 69, 1092.
- 21 Binnemans, K.; van Herck, K; Gorller-Walrand, C., Chem. Phys. Lett. 1997, 266, 297.
