A New Two-dimensional Cyano-bridged Chromium (HI)-Nickel (II) Bimetallic Assembly with Stair-like Layers
Xiao-Ping Shen
Department of Chemistry, Zhenjiang Teacher's College, Zhenjiang, Jiangsu 212003, China
Search for more papers by this authorAi-Hua Yuan
Department of Material and Environmental Engineering, East China Shipbuilding Institute, Zhenjiang, Jiangsu 212003, China
Search for more papers by this authorQiang-Jin Wu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorZi-Xiang Huang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorZheng Xu
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorYun-Peng Yu
Department of Chemistry, Zhenjiang Teacher's College, Zhenjiang, Jiangsu 212003, China
Search for more papers by this authorXiao-Ping Shen
Department of Chemistry, Zhenjiang Teacher's College, Zhenjiang, Jiangsu 212003, China
Search for more papers by this authorAi-Hua Yuan
Department of Material and Environmental Engineering, East China Shipbuilding Institute, Zhenjiang, Jiangsu 212003, China
Search for more papers by this authorQiang-Jin Wu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorZi-Xiang Huang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Search for more papers by this authorZheng Xu
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
Search for more papers by this authorYun-Peng Yu
Department of Chemistry, Zhenjiang Teacher's College, Zhenjiang, Jiangsu 212003, China
Search for more papers by this authorAbstract
From the reaction of K3[Cr(CN)6] and [NiL](CIO4)2 (L= 1,8-di(hydroxyethyl)-l, 3, 6, 8, 10, 13-hexaazacyclotetradecane), an infinite stair-like layered assembly [NiL]3 [Cr-(CN)6]2-6.5H2O is obtained, in which each hexacyanochromate(III) ion connects three nickel(II) ions using three cis Of groups and the bridging cyanide ligands coordinate to the nickel ion in a trans fashion forming trans-NiL(N°C)2 moieties.
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