Allylation of Diselenides, Aldehydes and Ketones with Ytterbium/Allyl Bromide System
Wei-Ke Su
Department of Chemistry, Zhejiang University (Campus Xixi), Hang Zhou, Zhejiang 310028, China
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorYong-Min Zhang
Department of Chemistry, Zhejiang University (Campus Xixi), Hang Zhou, Zhejiang 310028, China
Laboratory of Organometallic Chemistry, Chinese Academy of Science, Shanghai 200032, China
Search for more papers by this authorYong-Shu Li
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorWei-Ke Su
Department of Chemistry, Zhejiang University (Campus Xixi), Hang Zhou, Zhejiang 310028, China
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorYong-Min Zhang
Department of Chemistry, Zhejiang University (Campus Xixi), Hang Zhou, Zhejiang 310028, China
Laboratory of Organometallic Chemistry, Chinese Academy of Science, Shanghai 200032, China
Search for more papers by this authorYong-Shu Li
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorAbstract
In the presence of methyliodide, ytterbium can react with allyl bromide smoothly to form allylytterbium bromide, which further reacts with diselenides, aldehydes and ketones to afford allylselenides and homoallylic alcohols respectively in good yields under mild and neutral conditions.
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