Bite Angle Effects in Hydroformylation Catalysis†
Piet W. N. M. van Leeuwen
Institute of Molecular Chemistry, Homogeneous Catalysis, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
Search for more papers by this authorPaul C. J. Kamer
Institute of Molecular Chemistry, Homogeneous Catalysis, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
Search for more papers by this authorLars A. van Der Veen
Institute of Molecular Chemistry, Homogeneous Catalysis, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
Search for more papers by this authorJoost N. H. Reek
Institute of Molecular Chemistry, Homogeneous Catalysis, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
Search for more papers by this authorPiet W. N. M. van Leeuwen
Institute of Molecular Chemistry, Homogeneous Catalysis, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
Search for more papers by this authorPaul C. J. Kamer
Institute of Molecular Chemistry, Homogeneous Catalysis, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
Search for more papers by this authorLars A. van Der Veen
Institute of Molecular Chemistry, Homogeneous Catalysis, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
Search for more papers by this authorJoost N. H. Reek
Institute of Molecular Chemistry, Homogeneous Catalysis, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
Search for more papers by this authorSpecial paper from the “ China-Netherlands Bilateral Symposium on Organometallic Chemistry and Catalysis”, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China, 1999.
Abstract
Recent advances in rhodium catalyzed hydroformylation using xanthene-based ligands will be reviewed. The calculated natural bite angles of the ligands discussed are in the range 100–123°. While the general trend is clear—higher 1: b ratios at wider angles, small changes in the bite angle do not exhibit a regular effect on the selectivity of the reaction. The same is true for the rate of CO dissociation; the larger the rate of the CO dissociation, the larger the rate of hydroformylation, but for small changes the effects do not comply with this rule.
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