Volume 16, Issue 5 pp. 397-403

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EPR Study on the complex formed by charge-transfer process between ground-state acceptor chloranil and nine donors

Shi Ji-Liang,

Shi Ji-Liang

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Zhou Cheng-Ming,

Zhou Cheng-Ming

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Yi Hu-Nan,

Yi Hu-Nan

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Qiu Zhi-Hai,

Qiu Zhi-Hai

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Fu Yao-Hong,

Fu Yao-Hong

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Jiang Xi-Kui,

Jiang Xi-Kui

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Shi Ji-Liang,

Shi Ji-Liang

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Zhou Cheng-Ming,

Zhou Cheng-Ming

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Yi Hu-Nan,

Yi Hu-Nan

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Qiu Zhi-Hai,

Qiu Zhi-Hai

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Fu Yao-Hong,

Fu Yao-Hong

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Jiang Xi-Kui,

Jiang Xi-Kui

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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First published: 27 August 2010

https://doi.org/10.1002/cjoc.19980160503

Citations: 2

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Abstract

EPR study showed that the semi-quinone radical anion of chloranil (TCQ) was formed in a charge-transfer process between ground state chloranil as acceptor and each one of the following ground state donors, i.e., N, N-diethyl aniline (DEA), phenothiazine (PTZ), carbazole (CBZ), pyrene (PY), ferrocene (FRO), triphenylphosphine (TPP), triethylamine (TEA), anthracene (AN) and N, N-diethyl-3-aminophenyl ester of palmitic acid (DPP). Our results indicate that there is a tunneling effect for the ground-state charge-transfer process between chloranil and the donor.

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Volume16, Issue5

September 1998

Pages 397-403

EPR Study on the complex formed by charge-transfer process between ground-state acceptor chloranil and nine donors

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EPR Study on the complex formed by charge-transfer process between ground-state acceptor chloranil and nine donors

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