Volume 15, Issue 1 pp. 68-75
Article
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Studies of the dissociation and the protonation of TB-chlorosulphophenol

Chuan-Zhmg Zhu

Corresponding Author

Chuan-Zhmg Zhu

Department of Chemistry, East China Normal University, Shanghai 200062, China

Department of Chemistry, East China Normal University, Shanghai 200062, ChinaSearch for more papers by this author
Bao-Lin Yang

Bao-Lin Yang

Department of Chemistry, East China Normal University, Shanghai 200062, China

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Hong Zhao

Hong Zhao

Department of Chemistry, East China Normal University, Shanghai 200062, China

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Wen-Xiu Gu

Wen-Xiu Gu

Department of Chemistry, East China Normal University, Shanghai 200062, China

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Shi-Yun Ai

Shi-Yun Ai

Department of Chemistry, East China Normal University, Shanghai 200062, China

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First published: 27 August 2010
Citations: 3

Abstract

The dissociation constant of each step for TB-chlorosulphophenol has been determined by potentiometric method, and the thermodynamic constants. ΔG°, ΔH° and ΔS°, of the dissociation p- have been calculated. The protonation constants were measured by the spectrophotometric method. The pH values of various forms of anions of the chromogenic reagent at their concentrations were also calculated.

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