ChemInform Abstract: Reactions of Hydroxyl Group Containing Cyclic Acetals with Diazo Compounds.
Abstract
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ChemInform Abstract
Catalytic reaction of hydroxymethyl-containing cyclic acetals (I) and (IV) with diazomethane or diazoacetate (II) proceeds with introduction of the carbene into the hydroxyl O—H bond to furnish the corresponding ethers (III) and (V).