Volume 33, Issue 16
Preparative Organic Chemistry
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ChemInform Abstract: Reactions of Hydroxyl Group Containing Cyclic Acetals with Diazo Compounds.

D. A. Petrov

D. A. Petrov

Inst. org. khim. Ural. otd. Ross. Akad. nauk, Ufa 450054, Russia

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S. S. Zlotsky

S. S. Zlotsky

Inst. org. khim. Ural. otd. Ross. Akad. nauk, Ufa 450054, Russia

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R. M. Sultanova

R. M. Sultanova

Inst. org. khim. Ural. otd. Ross. Akad. nauk, Ufa 450054, Russia

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V. A. Dokichev

V. A. Dokichev

Inst. org. khim. Ural. otd. Ross. Akad. nauk, Ufa 450054, Russia

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First published: 22 May 2010

Abstract

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ChemInform Abstract

Catalytic reaction of hydroxymethyl-containing cyclic acetals (I) and (IV) with diazomethane or diazoacetate (II) proceeds with introduction of the carbene into the hydroxyl O—H bond to furnish the corresponding ethers (III) and (V).

chemical structure image

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