Heterocyclic Compounds
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ChemInform Abstract: A Simple and Efficient Aerobic Epoxidation of Alkenes by a Novel μ-Dimethoxo-Bridged Diferric Salen Derivative.
First published: 22 May 2010
Abstract
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ChemInform Abstract
The μ-dimethoxo diferric salen derivative DMDIFS is a novel and efficient catalyst for aerobic epoxidation of olefins in the presence of molecular oxygen and isobutyraldehyde as the reductant. The better β-selectivity with cholesterol (I) and the excellent yields with electron deficient olefins such as (IV) are examples for the variety of this epoxidation.
