Volume 32, Issue 45
Organoelement Compounds
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ChemInform Abstract: Zn/ZrCl4 System Induced Reductive Cleavage of the Se—Se Bond in Diaryl Diselenides: A Novel Method for the Synthesis of β-Selenoesters and β-Selenonitriles.

Songlin Zhang

Songlin Zhang

Coll. Chem. Environ. Sci., Henan Norm. Univ., Xinxiang, Henan 453002, Peop. Rep. China

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Fengshou Tian

Fengshou Tian

Coll. Chem. Environ. Sci., Henan Norm. Univ., Xinxiang, Henan 453002, Peop. Rep. China

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First published: 23 May 2010

Abstract

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ChemInform Abstract

The Se—Se bond in diselenides is reduced by Zn/ZrCl4 to produce selenoate anions which react with α,β-unsaturated esters or nitriles to afford title compounds (III).

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