Volume 32, Issue 45
Isocyclic Compounds
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ChemInform Abstract: Stereoselective Electrochemical Transformation of 4-Substituted Cyclohexanones into cis-5-Substituted-2,2-dimethoxycyclohexanols.

Michail N. Elinson

Michail N. Elinson

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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Sergey K. Feducovich

Sergey K. Feducovich

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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Dmitry E. Dmitriev

Dmitry E. Dmitriev

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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Alexnader S. Dorofeev

Alexnader S. Dorofeev

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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Anatolii N. Vereshchagin

Anatolii N. Vereshchagin

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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Gennady I. Nikishin

Gennady I. Nikishin

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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First published: 23 May 2010

Abstract

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ChemInform Abstract

Electrolysis of a methanolic solution of sodium halide and 4-substituted cyclohexanones (I) in an undivided cell results in a diastereoselective formation of the α-hydroxyketals (III).

chemical structure image

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