Volume 32, Issue 18
Organoelement Compounds
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ChemInform Abstract: An Efficient Entry to Monoiminophosphoranes Derived from 1,2-Bis(diphenylphosphino)ethane: New Bidentate P,N Ligands.

Mateo Alajarin

Mateo Alajarin

Dep. Quim. Org., Fac. Quim., Univ. Murcia, E-30071 Murcia, Spain

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Carmen Lopez-Leonardo

Carmen Lopez-Leonardo

Dep. Quim. Org., Fac. Quim., Univ. Murcia, E-30071 Murcia, Spain

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Pilar Llamas-Lorente

Pilar Llamas-Lorente

Dep. Quim. Org., Fac. Quim., Univ. Murcia, E-30071 Murcia, Spain

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First published: 27 May 2010

Abstract

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ChemInform Abstract

Base-promoted Michael-type addition of diphenylphosphine to the vinyliminophosphoranes (III) easily yields the heteroditopic P,N-donor ligands (V). Their coordination ability is tested by the reaction of (Vb) with dichlorobis(benzonitrile)palladium(II).

chemical structure image

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