Volume 32, Issue 18
Heterocyclic Compounds
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ChemInform Abstract: Cyclodimerization of Indol-2-ylacetylenes. An Example of Intermolecular Enyne—Alkyne Cycloaddition.

Daniele Passarella

Daniele Passarella

Dip. Chim. Org. Ind., Univ. Stud. Milano, CNR, I-20133 Milano, Italy

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Alessandra Giardini

Alessandra Giardini

Dip. Chim. Org. Ind., Univ. Stud. Milano, CNR, I-20133 Milano, Italy

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Marisa Martinelli

Marisa Martinelli

Dip. Chim. Org. Ind., Univ. Stud. Milano, CNR, I-20133 Milano, Italy

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Alessandra Silvani

Alessandra Silvani

Dip. Chim. Org. Ind., Univ. Stud. Milano, CNR, I-20133 Milano, Italy

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First published: 27 May 2010

Abstract

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ChemInform Abstract

Thermal cyclodimerization of indolylacetylenes (I) proceeds through an enyne—alkyne cycloaddition reaction to give indolylcarbazole derivatives (II). The reaction proceeds only in the presence of electron-withdrawing substituents at the alkyne side chain.

chemical structure image

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