Preparative Organic Chemistry
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ChemInform Abstract: Syn Diastereoselectivity in the Synthesis of Homoallylamine Using Crotylsilane in the Three-Component Reaction.
First published: 27 May 2010
Abstract
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ChemInform Abstract
The use of crotylsilane (II) in the Lewis acid catalyzed three-component reaction with aldehydes and carbamates gives generally homoallylamines with good syn selectivity under the optimized conditions A). The products can be transformed into pyrrolidines and piperidines.
