Volume 32, Issue 7
Heterocyclic Compounds
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ChemInform Abstract: Synthesis of New Dihydroxy-Dioxygenated ortho[2,x]Cyclophanes.

Cristian Simion

Cristian Simion

Tohwa Inst. Sci., Tohwa Univ., Minami, Fukuoka 815, Japan

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Alina Simion

Alina Simion

Tohwa Inst. Sci., Tohwa Univ., Minami, Fukuoka 815, Japan

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Yoshiharu Mitoma

Yoshiharu Mitoma

Tohwa Inst. Sci., Tohwa Univ., Minami, Fukuoka 815, Japan

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Satoko Nagashima

Satoko Nagashima

Tohwa Inst. Sci., Tohwa Univ., Minami, Fukuoka 815, Japan

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Takatoshi Kawaji

Takatoshi Kawaji

Tohwa Inst. Sci., Tohwa Univ., Minami, Fukuoka 815, Japan

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Iwao Hashimoto

Iwao Hashimoto

Tohwa Inst. Sci., Tohwa Univ., Minami, Fukuoka 815, Japan

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Masashi Tashiro

Masashi Tashiro

Tohwa Inst. Sci., Tohwa Univ., Minami, Fukuoka 815, Japan

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First published: 30 May 2010

Abstract

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ChemInform Abstract

Title compounds (IV) are conveniently prepared by a basic Zn- or Al-promoted reductive cyclization of the dialdehydes (III). The cyclization proceeds with very high trans diastereoselectivity.

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