Volume 31, Issue 51
Natural Products
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ChemInform Abstract: Fluoride Ion-Mediated Intramolecular Aldol Cyclization of 7-(t-Butyldimethylsiloxy)-7-octenal.

Iwao Hachiya

Iwao Hachiya

Dep. Appl. Chem., Fac. Sci., Sci. Univ. Tokyo, Shinjuku, Tokyo 162, Japan

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Nobutaka Kobayashi

Nobutaka Kobayashi

Dep. Appl. Chem., Fac. Sci., Sci. Univ. Tokyo, Shinjuku, Tokyo 162, Japan

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Hiroyuki Kijima

Hiroyuki Kijima

Dep. Appl. Chem., Fac. Sci., Sci. Univ. Tokyo, Shinjuku, Tokyo 162, Japan

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Khanitha Pudhom

Khanitha Pudhom

Dep. Appl. Chem., Fac. Sci., Sci. Univ. Tokyo, Shinjuku, Tokyo 162, Japan

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Teruaki Mukaiyama

Teruaki Mukaiyama

Dep. Appl. Chem., Fac. Sci., Sci. Univ. Tokyo, Shinjuku, Tokyo 162, Japan

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First published: 31 May 2010

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

ChemInform Abstract

A successful method for the preparation of eight-membered rings by fluoride ion mediated intramolecular aldol cyclization leads to the key intermediate (XI) of taxol and to ring systems, e.g. (XIII).

chemical structure image

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