Volume 31, Issue 51
Heterocyclic Compounds
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ChemInform Abstract: A Two-Component Pericyclic Reaction for Synthesis of Substituted Benzofurans and Aryl—Quaternary Carbon Bonds.

James B. Hendrickson

James B. Hendrickson

Dep. Chem., Brandeis Univ., Waltham, MA 02454, USA

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Martin A. Walker

Martin A. Walker

Dep. Chem., Brandeis Univ., Waltham, MA 02454, USA

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First published: 31 May 2010

Abstract

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ChemInform Abstract

Formation of the title compounds is proposed to proceed via a new, charge-accelerated [3,3]-sigmatropic rearrangement involving an O-arylsulfoxonium species generated from a phenol and a vinyl sulfoxide activated by TFAA.

chemical structure image

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