Volume 31, Issue 51
Heterocyclic Compounds
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ChemInform Abstract: Intermolecular Asymmetric Heck Reactions with 2,2-Diethyl-2,3-dihydrofuran.

Alan J. Hennessy

Alan J. Hennessy

Dep. Chem., Univ. Coll., Belfield, Dublin 4, Ire.

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David J. Connolly

David J. Connolly

Dep. Chem., Univ. Coll., Belfield, Dublin 4, Ire.

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Yvonne M. Malone

Yvonne M. Malone

Dep. Chem., Univ. Coll., Belfield, Dublin 4, Ire.

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Patrick J. Guiry

Patrick J. Guiry

Dep. Chem., Univ. Coll., Belfield, Dublin 4, Ire.

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First published: 31 May 2010

Abstract

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ChemInform Abstract

In the presence of chiral phosphinamine (or diphosphine) ligands, the asymmetric Heck reaction of 2,2-diethyl-2,3-dihydrofuran and triflates (II) is investigated giving 2,5-dihydrofurans with up to 94% e.e.

chemical structure image

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