Isocyclic Compounds
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ChemInform Abstract: Synthesis, Structure, and Properties of Hexaaryl[3]radialenes.
First published: 31 May 2010
Abstract
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ChemInform Abstract
A number of hexaaryl[3]radialenes (III) are synthesized in moderate to good yields by reaction of tetrachloropropene with the carbanions of substituted diphenylmethanes followed by oxidation with oxygen. Especially, diarylmethanes with high acidity afford good yields of radialenes. Except for hexanitro compound (IIId) all radialenes are fairly stable substances.
