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ChemInform Abstract: An Unusual Side Reaction in the Perallylation of a Glucoside Brought About by Sodium Hydride.
First published: 03 June 2010
Abstract
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ChemInform Abstract
In the case of the Williamson perallylation of the functionalized glucoside (I) an unexpected side product (IV) is formed. Cleavage of the ester and formation of the free carboxylate, induced by the nucleophilic sodium hydride agent, is assumed.
