Heterocyclic Compounds
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ChemInform Abstract: A Short Total Synthesis of Cerpegin (VI) by Intramolecular Hetero Diels—Alder Cycloaddition Reaction of an Acetylene-Tethered Pyrimidine.
First published: 03 June 2010
Abstract
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ChemInform Abstract
The title synthesis uses the readily available 4,6-dichloropyrimidine-5-carbaldehyde as starting material. Key feature is an intramolecular hetero Diels—Alder reaction of the pyrimidine to an alkyne function.
