Volume 31, Issue 34
Physical Inorganic Chemistry
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ChemInform Abstract: Crystal Structure and Spectroscopic Data of Silver Cyanamide.

Michael Becker

Michael Becker

MPI Festkoerperforsch., D-70569 Stuttgart, Germany

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Juergen Nuss

Juergen Nuss

MPI Festkoerperforsch., D-70569 Stuttgart, Germany

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Martin Jansen

Martin Jansen

MPI Festkoerperforsch., D-70569 Stuttgart, Germany

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First published: 03 June 2010

Abstract

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ChemInform Abstract

Single crystals of Ag2CN2 are grown from aq. NH3 solutions of AgNO3 and H2CN2. The compound crystallizes in the monoclinic space group P21/c with Z = 4. The slightly bent CN22- anion exhibits two significantly different C—N bond lengths of 1.194 and 1.266 Å, respectively.

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