Volume 31, Issue 25
Natural Products
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ChemInform Abstract: First Total Synthesis of 11-Thia Steroids.

Frederic Cachoux

Frederic Cachoux

Lab. Synth. Org., CNRS, Fac. Sci. St. Jerome, Univ. Aix-Marseille III, F-13397 Marseille, Fr.

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Malika Ibrahim-Ouali

Malika Ibrahim-Ouali

Lab. Synth. Org., CNRS, Fac. Sci. St. Jerome, Univ. Aix-Marseille III, F-13397 Marseille, Fr.

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Maurice Santelli

Maurice Santelli

Lab. Synth. Org., CNRS, Fac. Sci. St. Jerome, Univ. Aix-Marseille III, F-13397 Marseille, Fr.

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First published: 07 June 2010

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

ChemInform Abstract

The key step in the synthesis of 11-thia steroids is the intramolecular Diels—Alder cycloaddition of an o-quinodimethane intermediate generated in situ from the benzocyclobutene (II).

chemical structure image

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