Physical Inorganic Chemistry
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ChemInform Abstract: Barium Vanadium(III) Hydrogen Phosphate, Ba3V2(HPO4)6.
First published: 07 June 2010
Abstract
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ChemInform Abstract
Single crystals of the title compound are grown hydrothermally from an aqueous solution of BaCO3, VCl3, H3PO4, and guanidinium carbonate (453 K, 24 h; autoclave). Ba3V2(HPO4)6 crystallizes in the trigonal space group R
c with Z = 6. The structure consists of a three-dimensional network of corner-sharing VIIIO6 octahedra and HPO4 tetrahedra. The Ba2+ cations are in 12-fold coordination.
