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ChemInform Abstract

The Pd/BINAP catalyst system is highly effective for the arylation of primary amines. A variety of substrate combinations are tolerated, including amines that are branched or contain functional groups such as olefins or acetals. Good results can also be obtained for arylation of secondary amines, although acyclic secondary amines often react poorly under these conditions. A wide variety of functional groups such as ester, nitrile, nitro groups, and enolizable ketones are tolerated when the mild base Cs₂CO₃ is employed.