Volume 31, Issue 23
Preparative Organic Chemistry
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ChemInform Abstract: Highly Regio- and Stereoselective Cycloreductions of 1,6- and 1,7-Enynes Activated with a Carbonyl Functionality.

Chang Ho Oh

Chang Ho Oh

Dep. Chem., Hanyang Univ., Seoul 133-791, S. Korea

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Hyung Hoon Jung

Hyung Hoon Jung

Dep. Chem., Hanyang Univ., Seoul 133-791, S. Korea

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Joo Sung Kim

Joo Sung Kim

Dep. Chem., Hanyang Univ., Seoul 133-791, S. Korea

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Seung Woo Cho

Seung Woo Cho

Dep. Chem., Hanyang Univ., Seoul 133-791, S. Korea

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First published: 08 June 2010

Abstract

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ChemInform Abstract

A highly regio- and stereoselective cycloreduction of 1,6- and 1,7-enynes, in which the alkyne unit is conjugated with an electron withdrawing group, to γ,δ-unsaturated compounds is reported. Mechanistically, a two-step β-elimination—reduction sequence is assumed.

chemical structure image

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