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ChemInform Abstract: Enantioselective Syntheses of 2-Alkyl- and 2,6-Dialkylpiperidine Alkaloids: Preparations of the Hydrochlorides of (-)-Coniine, (-)-Solenopsin A, and (-)-Dihydropinidine.
First published: 09 June 2010
Abstract
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ChemInform Abstract
Based on the enantioselective hydrogenation of the tetrahydropyridine (I) and a diastereoselective lithiation—substitution, a highly enantioselective synthesis of the title compounds is achieved via the common intermediate (II).
