ChemInform Abstract: Synthesis, Structure, and Reactivity of Functionalized Stibanido Complexes of Iron and Ruthenium [(η5-C5Me5) (CO)2MSbR1R2] (M: Fe, Ru; R1, R2: SiMe3, C(O)tBu, C(O)Ph, C(O)-1 Ad).
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract
Reaction of the corresponding bis(trimethylsilyl) stibanido complexes of ruthenium with equivalent amounts of acyl chlorides yields mixed acyl(trimethylsilyl)stibanido complexes (IIa), (IIb), and (IIc), whereas reaction with two molar equivalents of acyl chlorides affords the diacylstibanido complexes (IId) and (IIe). In case of the iron complexes (I) excess amounts of acyl chlorides are necessary. The molecular structures of (IIa) and (IIe) are elucidated by single crystal X-ray analysis.
