Volume 31, Issue 16
Heterocyclic Compounds
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ChemInform Abstract: Cyclodimerization of the 4-Oxo Derivative of Pummerer′s Ketone.

G. W. Kirby

G. W. Kirby

Dep. Chem., Univ. Glasgow, Glasgow G12 8QQ, UK

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S. Jayakumar

S. Jayakumar

Dep. Chem., Univ. Glasgow, Glasgow G12 8QQ, UK

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R. Senthil Kumar

R. Senthil Kumar

Dep. Chem., Univ. Glasgow, Glasgow G12 8QQ, UK

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Mohinder P. Mahajan

Mohinder P. Mahajan

Dep. Chem., Univ. Glasgow, Glasgow G12 8QQ, UK

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First published: 09 June 2010

Abstract

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ChemInform Abstract

Pummerer′s ketone (I) is converted by selenium dioxide into the enolic form of its 4-oxo derivative (III) which undergoes an unexpected dimerization furnishing a symmetrical caged dimer after chromatography.

chemical structure image

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